By W G Frankenburg; V I Komarewsky; Eric K Rideal
ADVANCES IN CATALYSIS quantity 3.
content material: entrance hide; Advances in Catalysis and comparable topics, quantity III; Copyright web page; Contents; members to quantity III; Editors' Preface; bankruptcy 1. Balandin's Contribution to Heterogeneous Catalysis; I. creation; II. The Multiplet thought; III. dialogue of the speculation; IV. Steric issues in Catalysis; References; bankruptcy 2. Magnetism and the constitution of Catalytically lively Solids; I. advent; II. common rules; III. Experimental equipment; IV. The Susceptibility Isotherm; V. Supported Chromium Oxide; VI. Supported Oxides of Manganese; VII. Supported Nickel Oxide VIII. Supported Iron OxideIX. Supported Copper Oxide; X. comparable platforms; XI. Self-Supported structures; XII. Ferromagnetism; XIII. identity of Ferromagnetic levels; XIV. response techniques; XV. answer techniques; XVI. precis; References; bankruptcy three. Catalytic Oxidation of Acetylene in Air for Oxygen Manufacture; I. advent; II. of Air and Acetylene; III. Acetylene removing; IV. Catalyst Compositions; V. Regeneration; VI. Mechanism of the Oxidation Reactions; VII. Mechanism of the Oxidation through Silver Nitrate; References; bankruptcy four. The Poisoning of metal Catalysts I. Catalysts at risk of PoisoningII. relevant forms of Catalyst Poisons; III. the shape of Catalyst Poisoning Curves; IV. additional elements Influencing Toxicity; V. priceless Poisoning; References; bankruptcy five. Catalytic Cracking of natural Hydrocarbons; I. advent; II. Catalytic Cracking Reactions; III. Catalytic Cracking of Paraffins; IV. Catalytic Cracking of Olefins; V. Catalytic Cracking of Naphthenes; VI. Catalytic Cracking of fragrant Hydrocarbons; VII. constitution of Cracking Catalysts; References; bankruptcy 6. Chemical features and constitution of Cracking Catalysts I. IntroductionII. size of the "Acidity" of Cracking Catalysts; III. id of the Acid facilities because the Catalytically energetic websites; IV. constitution of the Acid; V. Mechanism of Hydrocarbon Reactions on a Cracking Catalyst; References; bankruptcy 7. response premiums and Selectivity in Catalyst Pores; I. creation; III . The actual photograph of the Pore constitution; III. Mechanism of shipping in Catalyst Pores; IV. actual elements settling on response charges on Porous Catalysts . (Definition of fee Constants, the basic Differential Equation and the legislations of Conservation of Mass V. response charges in unmarried PoresVI. response charges on functional Catalyst Pellets; VII. response charges on Poisoned Catalysts (Apparent Selective Poisoning); VIII. impression of Pore constitution on Catalyst Selectivity; Appendix; thesaurus of Symbols; References; bankruptcy eight. Nickel Sulfide Catalysts; I. creation; II. The Nickel-Sulfur Equilibrium; III. actual Adsorption of Gases on Ni2S2 Catalysts; IV. Chemisorption of Gases on Ni2S2; V. helps for Stabilizing Nickel Sulfide; VI. education of Nickel Sulfide Catalysts; VII. priceless existence and Regeneration
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98 3. Magnetic Data . . . . . . . . . . . . . . . . . . . . . . . . . 100 4. Diffusion in Powdered Metals.. 101 5. Interpretation of Morris-Selwoo . . . . . . . . . . . 102 . . . . . . . 104 Summary.. . . . . . . . . . . . . . References . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105 I. INTRODUCTION The principal application of magnetic methods to catalysis has been the elucidation of structure in certain classes of active eiements and compounds.
In this connection, the following points are noted. a) Beeck (34) has shown that ethylene chemisorption takes place rapidly, with dissociation of hydrogen, according t o the equation 4M + CoHl-+ 2MH + MtCzHz. The C-H bond thus breaks, even in preference to the weak r bond which forms the second link of the C=C double bond. b) Extensive investigations on the reactions of hydrocarbons a t nickel surfaces have been made by Taylor and his co-workers (42, 43, 44). This work showed that exchange of the saturated paraffin hydrocarbons with deuterium took place at lower temperatures than the hydrogenation reactions with splitting of C-C bonda.
93 2. Cobalt Carbide . . . . . . . . . . . . . . . . . . . . . . . . . 96 Solution Processes. . . . . . . . . . . . . . . 1. Introduction. . . . . 2. Catalyst Preparation. . . . . . . . . . . . . . . . . 98 3. Magnetic Data . . . . . . . . . . . . . . . . . . . . . . . . . 100 4. Diffusion in Powdered Metals.. 101 5. Interpretation of Morris-Selwoo . . . . . . . . . . . 102 .
Advances in catalysis by W G Frankenburg; V I Komarewsky; Eric K Rideal